Sindh Board Chemistry 12th Solved Questions provides comprehensive answers to key topics in the chemistry curriculum. This resource covers essential concepts such as d-block elements, flame tests, and mass spectrometry, making it ideal for students preparing for exams. Detailed explanations of chemical reactions, properties of compounds, and various organic and inorganic chemistry topics are included. Perfect for Sindh Board students, this guide aids in understanding complex chemistry principles and enhances exam readiness.

Key Points

  • Includes solved questions on d-block elements and their properties.
  • Covers flame test results for alkali and alkaline earth metals.
  • Explains the preparation and properties of nylon and PVC.
  • Details the manufacture of caustic soda by the Castner-Kellner process.
Faizan Shareef
13 pages
Language:English
Type:Solution Manual
Faizan Shareef
13 pages
Language:English
Type:Solution Manual
Faizan Shareef
13 pages
Language:English
Type:Solution Manual
166

Sindh Board Chemistry 12th Solved Questions pdf

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CLASS 12 CHEMISTRY – SOLVED QUESTIONS
Sindh Board English Medium (Section B & C)
SECTION B – INORGANIC
Q1. What is bleaching powder? How is it prepared? Give its reaction
with water and HCl.
Answer:
Bleaching powder is a chemical compound having formula CaOCl₂. It is also called calcium oxychloride.
Preparation:
Bleaching powder is prepared by passing chlorine gas over dry slaked lime Ca(OH)₂.
Equation:
Ca(OH)₂ + Cl₂ CaOCl₂ + H₂O
Reaction with Water:
CaOCl₂ + H₂O Ca(OH)₂ + Cl₂
Reaction with HCl:
CaOCl₂ + 2HCl CaCl₂ + H₂O + Cl₂
Q2. What is flame test? Mention the flame colors of alkali and
alkaline earth metals.
Answer:
Flame test is a method used to identify metals by observing the color produced in flame.
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Flame Colors:
Metal Flame Color
Lithium Crimson red
Sodium Golden yellow
Potassium Violet
Calcium Brick red
Strontium Crimson
Barium Apple green
Q3. Define d-block elements. Why do they form colored
compounds? Explain crystal field theory.
Answer:
d-block Elements:
Elements in which the last electron enters d-orbital are called d-block elements.
Reason for Colored Compounds:
Transition metals have partially filled d-orbitals. Electrons absorb visible light and jump between d-orbitals,
producing color.
Crystal Field Theory:
According to crystal field theory, ligands surrounding the metal ion split the d-orbitals into different energy
levels. Electrons absorb energy to move from lower to higher level, causing color.
Q4. Define ligands and classify them on the basis of donor sites.
Answer:
Ligands are atoms, ions or molecules which donate electron pairs to central metal atom.
Classification:
Monodentate Ligands: Donate one electron pair. Example: NH₃, Cl⁻1.
2
Bidentate Ligands: Donate two electron pairs. Example: Ethylene diamine
Polydentate Ligands: Donate many electron pairs. Example: EDTA
Q5. Define mass spectrometry. Give its applications.
Answer:
Mass spectrometry is an analytical technique used to determine molecular mass and structure of
compounds.
Information Obtained:
Molecular mass
Molecular formula
Structure of molecule
Isotopes present
Applications:
Identification of compounds
Determination of molecular structure
Medical analysis
Petroleum industry
Q6. Describe preparation and two properties of nylon and PVC.
Answer:
Nylon:
Preparation:
Nylon is prepared by condensation polymerization of adipic acid and hexamethylene diamine.
Properties:
Strong and elastic
Resistant to chemicals
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FAQs

What is bleaching powder and how is it prepared?
Bleaching powder, known chemically as calcium oxychloride with the formula CaOCl₂, is prepared by passing chlorine gas over dry slaked lime (Ca(OH)₂). The reaction can be represented as Ca(OH)₂ + Cl₂ → CaOCl₂ + H₂O. When bleaching powder reacts with water, it produces calcium hydroxide and chlorine gas, as shown in the equation CaOCl₂ + H₂O → Ca(OH)₂ + Cl₂. Additionally, when it reacts with hydrochloric acid (HCl), it forms calcium chloride, water, and chlorine gas: CaOCl₂ + 2HCl → CaCl₂ + H₂O + Cl₂.
What are the flame colors of alkali and alkaline earth metals?
The flame test is a method used to identify metals based on the color they produce in a flame. For alkali metals, lithium produces a crimson red flame, sodium gives a golden yellow flame, and potassium shows a violet flame. In contrast, alkaline earth metals exhibit different colors: calcium produces a brick red flame, strontium shows a crimson flame, and barium gives an apple green flame. These distinct colors help in the identification of these metals in various chemical analyses.
What is crystal field theory and its significance?
Crystal field theory explains the behavior of transition metal complexes, particularly regarding their color. According to this theory, ligands surrounding a metal ion cause the d-orbitals to split into different energy levels. This splitting allows electrons to absorb energy and transition between d-orbitals, which results in the absorption of visible light and the appearance of color in the compounds. The presence of partially filled d-orbitals in transition metals is crucial for this phenomenon, as it leads to the formation of colored compounds.
What is the preparation method for nylon?
Nylon is synthesized through the process of condensation polymerization, specifically from adipic acid and hexamethylene diamine. This reaction results in the formation of long-chain polyamide molecules, which exhibit strong and elastic properties. Nylon is known for its resistance to chemicals, making it a valuable material in various applications, including textiles and engineering.
How does the boiling point of halogens change down the group?
The boiling point of halogens increases as you move down the group in the periodic table. This trend is attributed to the increase in molecular size and the corresponding rise in van der Waals forces between the molecules. As the size of the halogen atoms increases, the strength of these intermolecular forces also increases, leading to higher boiling points for the heavier halogens.
What defines d-block elements and their unique properties?
D-block elements are defined as those elements in which the last electron enters a d-orbital. These transition metals exhibit unique properties, such as the ability to form colored compounds due to their partially filled d-orbitals. The presence of these d-orbitals allows for d-d transitions, where electrons absorb visible light, contributing to the characteristic colors of these compounds. Additionally, d-block elements often have variable oxidation states, making them versatile in chemical reactions.
What is the significance of the Baeyer test for ethane?
The Baeyer test is used to detect the presence of unsaturation in organic compounds. In the case of ethane, it does not decolorize potassium permanganate (KMnO₄), indicating that ethane is a saturated hydrocarbon with no double or triple bonds. This test is significant as it helps differentiate between saturated and unsaturated compounds, providing insights into the chemical structure and reactivity of the substance being tested.